- 作 者：陆家政，陈菲主编
- 出 版 社：北京：化学工业出版社
- 出版年份：2009
- ISBN：9787122062505
- 标注页数：308 页
- PDF页数：318 页
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Ⅰ Inorganic Chemistry 1
Chapter 1 Introduction 2
1.1 Observations and Conclusions 3
1.2 The Scientific Method 3
1.3 Units of Measurement 5
1.4 Advice on Studying Chemistry 8
Key Words 8
Chapter 2 Structures of Atoms 9
2.1 Particles in Atoms 10
2.2 The Bohr Model 12
2.3 The Wave Theory of Electrons 13
2.4 Heisenberg's Uncertainty Principle 14
2.5 The Schr？dinger Equation 14
2.6 Quantum Numbers 15
2.7 Shapes of Atomic Orbitals 17
2.8·Many-Electron Atoms 19
2.9 Valence Electrons 24
2.10 The Periodic Table and Electronic Configurations of Atoms 24
2.11 The Periodicity of the Properties of Elements and Atomic Structure 26
Key Words 30
Exercises 31
Chapter 3 Chemical bonds 33
3.1 Ionic Bonds 33
3.2 Covalent Bonds 35
3.3 Lewis Dot Symbols and Lewis Structure 37
3.4 Sigma and Pi Bonds 43
3.5 Bond Polarity 44
3.6 Bond Energy，Bond Length and Bond Angle 45
3.7 Molecular Geometry 47
3.8 The VSEPR Model 47
3.9 Hybrid Orbitals 51
3.10 Molecular Orbitals 56
3.11 Intermolecular Force 64
Key Words 71
Exercises 71
Chapter 4 Thermochemistry 74
4.1 First Law of Thermodynamics 74
4.2 Enthalpy and Enthalpy Change 75
4.3 Hess's Law 76
4.4 Entropy and the Second Law of Thermodynamics 79
4.5 Spontaneous Processes and Gibbs Free Energy 80
4.6 Temperature and Direction of Spontaneous Change 81
4.7 Standard Free Energy of Formation and Standard Free Energy of Reaction 82
Key Words 83
Exercises 83
Chapter 5 Chemical Kinetics 85
5.1 Reaction Rates 85
5.2 Theories of Reaction Rates 87
5.3 Effect of Concentration on Rate of Reaction 89
5.4 Rate and Temperature 92
5.5 Catalysis 94
Key Words 95
Exercises 96
Chapter 6 Chemical Equilibrium 98
6.1 Concept of Equilibrium 98
6.2 Equilibrium Constant 98
6.3 Le Ch？telier's Principle 103
Key Words 106
Exercises 106
Chapter 7 Solutions 108
7.1 Ways of Expressing Concentration 108
7.2 Colligative Properties 113
Key Words 124
Exercises 125
Chapter 8 Solubility Equilibrium 127
8.1 Saturated Solutions and Solubility 127
8.2 Solubility Equilibria 127
8.3 Factors Affecting Solubility 130
8.4 Predicting Precipitation Reaction 132
8.5 Selective Precipitation 134
8.6 Application of Precipitate on Medicine 137
Key Words 138
Exercises 139
Chapter 9 Acid-Base Equilibria 141
9.1 Acids and Bases 141
9.2 Ion Product of Water 143
9.3 Strength of Weak Acids and Bases 144
9.4 The pH of Weak Acids and Bases 146
9.5 The Common-Ion Effect 148
9.6 Buffer Solutions 150
Key Words 153
Exercises 153
Chapter 10 An Introduction to Electrochemistry 155
10.1 Oxidation-Reduction Reactions 155
10.2 Balancing Oxidation-Reduction Equations 158
10.3 Voltaic Cells 161
10.4 Standard Cell Electromotive Force 164
10.5 Electrochemistry and Thermodynamics 171
10.6 Effect of Concentration on Cell EMF 172
10.7 Reduction Potential Diagrams of Elements(Latimer Diagrams) 174
Key Words 177
Exercises 177
Chapter 11 Chemistry of Coordination Compounds 180
11.1 The History of Coordination Chemistry 180
11.2 Formation of Coordination Compound 182
11.3 Nomenclature of Coordination Compounds 184
11.4 Structure and Isomerism 185
11.5 Coordination Equilibrium in Solution 187
11.6 Valence Bond Theory of Coordination Compounds 191
11.7 The Crystal Field Theory 194
11.8 The Biological Effects of Coordination Compounds 199
Key Words 200
Exercises 201
Chapter 12 Nonmetals and Semimetals 203
12.1 General Concepts 203
12.2 Hydrogen 203
12.3 Boron 204
12.4 The Group Ⅳ A Elements,the Carbon Group Elements 205
12.5 The Group Ⅴ A Elements,the Nitrogen Group Elements 208
12.6 The Group Ⅵ A Elements,the Oxygen Group Elements 211
12.7 The Group Ⅶ A Elements,the Halogens 215
12.8 The Group Ⅷ A Elements,the Noble Gases 218
Key Words 218
Exercises 219
Chapter 13 Metals 220
13.1 The Group IA Elements 220
13.2 The Group Ⅱ A Elements 224
13.3 The Group Ⅲ A Elements 229
13.4 A Survey of Transition Metals 232
13.5 Chemistry of Some Transition Metals 234
Key Words 239
Exercises 239
Ⅱ Inorganic Chemical Experiments 241
Chapter 1 Basic Techniques of Experimental Chemistry 242
1.1 Safety 242
1.2 Recording Results 243
1.3 Weighing 243
1.4 Concerning Liquids 244
Chapter 2 Typical Chemical Laboratory Apparatus 252
Chapter 3 Experiments 254
3.1 Some Elementary Operation 254
3.2 Acid-Base Titration 256
3.3 Electrolyte Solutions 259
3.4 Preparation of Officinal Sodium Chloride and Its Purity Examination 262
3.5 Oxidation-Reduction Reactions 267
3.6 Coordination Compounds 271
3.7 The Halogens 275
3.8 Chromium,Manganese and Iron 278
3.9 Copper,Silver,Zinc and Mercury 283
3.10 Determination of the Ionization Constant of HAc by pH Meter 287
3.11 Preparation of Ammonium Iron（Ⅱ）Sulfate 291
3.12 Preparation and Content Determination of Zinc Gluconate 294
Appendix 296
Reference 308